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101.
102.
银纳米颗粒与光子晶体光纤、表面增强拉曼散射效应结合而成的PCF SERS传感器得到了科研界的广泛关注.而PCF结构、SERS基底的性能是传感器的重要影响因素.为了进一步提高SERS PCF传感器的性能,通过研究对比PCF和SERS基底结构参数对传感性能的影响,设计出适用于PCF SERS传感的空芯PCF以及SERS基底的结构参数.通过数值计算,设计的空芯PCF空气填充率为56.30%,当激发光波长785 nm时存在光子带隙,并能够实现单模传输.而半径为38 nm的银纳米球在间距为0.7 nm时能够产生最大的SERS增强因子.研究证明,设计的空芯PCF在785 nm输入波长下既能够基模传输激发光,又能够为SERS提供理想的活性面积,而且银纳米颗粒的形状、尺寸、间距对SERS性能影响严重,而且与入射波长有很强的依赖关系. 相似文献
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Multifunctional Silver‐Exchanged Zeolite Micromotors for Catalytic Detoxification of Chemical and Biological Threats 下载免费PDF全文
Virendra V. Singh Beatriz Jurado‐Sánchez Sirilak Sattayasamitsathit Jahir Orozco Jinxing Li Michael Galarnyk Yuri Fedorak Joseph Wang 《Advanced functional materials》2015,25(14):2147-2155
Multifunctional reactive‐zeolite‐based micromotors have been developed and characterized toward effective and rapid elimination of chemical and biological threats. The incorporation of silver ions (Ag+) into aluminosilicate zeolite framework imparts several attractive functions, including strong binding to chemical warfare agents (CWA) followed by effective degradation, and enhanced antibacterial activity. The new zeolite‐micromotors protocol thus combines the remarkable adsorption capacity of zeolites and the efficient catalytic properties of the reactive Ag+ ions with the autonomous movement of the zeolite micromotors for an accelerated detoxification of CWA. Furthermore, the high antibacterial activity of Ag+ along with the rapid micromotor movement enhances the contact between bacteria and reactive Ag+, leading to a powerful “on‐the‐fly” bacteria killing capacity. These attractive adsorptive/catalytic features of the self‐propelled zeolite micromotors eliminate secondary environmental contamination compared to adsorptive micromotors. The distinct cubic geometry of the zeolite micromotors leads to enhanced bubble generation and faster movement, in unique movement trajectories, which increases the fluid convection and highly efficient detoxification of CWA and killing of bacteria. The attractive capabilities of these zeolite micromotors will pave the way for their diverse applications in defense, environmental and biomedical applications in more economical and sustainable manner. 相似文献
105.
Cohesively Enhanced Conductivity and Adhesion of Flexible Silver Nanowire Networks by Biocompatible Polymer Sol–Gel Transition 下载免费PDF全文
Yunxia Jin Lu Li Yuanrong Cheng Lingqiang Kong Qibing Pei Fei Xiao 《Advanced functional materials》2015,25(10):1581-1587
Silver nanowire (AgNW) networks are a promising candidate to replace indium tin oxide (ITO) as transparent conductors. In this paper, a novel transparent composite conductor composed of AgNW/biocompatible alginate gel on a flexible polyethylene terephthalate (PET) substrate, with synchronously enhanced adhesion and reduced resistivity, is prepared without high‐temperature annealing. The sheet resistance of the flexible AgNW/PET film reduces from 300 to 50.3 Ohm sq?1 at transmittance of 94%. The optical and electrical performance is superior to that obtained from the flexible ITO film on PET. Meanwhile, the sheet resistance does not show great change after tape test, suggesting a good adhesion of AgNW to the polymer substrate. Moreover, the AgNW composite film shows a good stability to resist long‐term storage, solvent damage, and ultrasonication. Finally, polymer solar cells employing the composite AgNW film as the electrode are realized, displaying an efficiency of 2.44%. 相似文献
106.
Locally Welded Silver Nano‐Network Transparent Electrodes with High Operational Stability by a Simple Alcohol‐Based Chemical Approach 下载免费PDF全文
Haifei Lu Di Zhang Jiaqi Cheng Jian Liu Jian Mao Wallace C. H. Choy 《Advanced functional materials》2015,25(27):4211-4218
As an indispensable aspect of emerging flexible optoelectronics, flexible transparent electrodes, especially those comprised of metal nanowires, have attracted great attentions recently. Welding the nanowire junctions is an effective strategy for reducing the sheet resistance and improving the operational stability of flexible nanowire electrode in practical applications. Herein, a simple alcohol‐based solution approach is proposed to weld crossed silver nanowires by chemically growing silver “solder” at the junctions of the nanowires, forming transparent silver nano‐network electrodes with improved electrical conductivity and operational stability. Remarkably, silver nano‐networks can be rapidly formed by this simple approach under ambient condition and room temperature, requiring no assistance from heat, light, electrical current, or mechanical pressure. Furthermore, our results show that the nano‐network electrode formed from large diameter nanowires offers a better operational stability, whose trend is opposite to that of the untreated electrodes. To demonstrate the potential application of the highly stable silver nano‐network from large diameter nanowires, organic solar cells fabricated on the nano‐network electrode incorporated with silicon dioxide nanoparticles achieve comparable performance to the ITO control device. Consequently, strategy demonstrated in this work can contribute to low‐cost and highly stable transparent electrodes in emerging flexible optoelectronics. 相似文献
107.
Synthetic Crystals of Silver with Carbon: 3D Epitaxy of Carbon Nanostructures in the Silver Lattice 下载免费PDF全文
Lourdes G. Salamanca‐Riba Romaine A. Isaacs Melburne C. LeMieux Jiayu Wan Karen Gaskell Yeping Jiang Manfred Wuttig Azzam N. Mansour Sergey N. Rashkeev Maija M. Kuklja Peter Y. Zavalij Jaime R. Santiago Liangbing Hu 《Advanced functional materials》2015,25(30):4768-4777
Only minimum amounts of carbon can be incorporated into silver, gold, and copper in a thermodynamically stable form. Here, the structure of stable silver carbon alloys is described, which are produced by thermoelectrically charging molten silver with carbon ions. Transmission electron microscopy and Raman scattering are combined to establish that large amount of carbon is accommodated in the form of epitaxial graphene‐like sheets. The carbon bonds covalently to the silver matrix as predicted from density functional theory (DFT) calculations with bond energies in the range 1.1–2.2 eV per atom or vacancy. Graphitic‐like sheets embedded in the crystal lattice of silver form 3D epitaxial structures with the host metal with a strain of ≈13% compared to equilibrium graphene. The carbon nanostructures persist upon remelting and resolidification. A DFT‐based analysis of the phonon density of states confirms the presence of intense vibration modes related to the Ag? C bonds observed in the Raman spectra of the alloy. The solid silver–high carbon alloy, termed “Ag‐covetic,” displays room temperature electrical conductivity of 5.62 × 107 S m?1 even for carbon concentrations of up to ≈6 wt% (36 at%). This process of incorporation of carbon presents a new paradigm for electrocharging assisted bulk processing. 相似文献
108.
109.
以Ag-65SnIn-8熔炼雾化粉体为原料,采用原位氧化工艺制备了Ag-60SnO2In2O3中间体粉体,与雾化纯银粉配比成Ag-92SnO2In2O3材料,通过混粉-等静压-烧结-热压-挤压技术制备Ag-92SnO2In2O3带材,再通过固相复合工艺制备所需要的Ag-92SnO2In2O3/Cu/Fe电接点材料。相对比常规氧化工艺制备的Ag-60SnO2In2O3中间体粉体制备的Ag-92SnO2In2O3/Cu/Fe电接点材料,原位氧化工艺制备的Ag-92SnO2In2O3/Cu/Fe电接点材料电阻率可达2.1μΩ.cm以下,硬度可达85~110HV;产品应用于380V,65A,功率因数0.7的电动机负载电路的热保护器中,电器寿命满足5000次分断要求,替代AgCdO/Cu/Fe电接点材料,实现环保,无镉化切换。 相似文献
110.
本文提出一种制备具有高金属覆载率及良好均匀性的PS/Ag复合微球的简便方法,可以避免PS微球的表面修饰。首先通过多元醇法制备具有良好单分散性的PVP覆盖的Ag纳米颗粒, 然后通过溶胀-异质凝聚法将这些Ag纳米颗粒负载于PS球上。对Ag纳米颗粒的尺寸分布及PS/Ag复合微球的表面形貌进行了研究,结果表明这种方法制得的PS/Ag复合微球具有良好的分散性与均一性,并且Ag颗粒的负载率可以通过Ag溶胶的加入量来调控。 相似文献